I came across Spherification earlier in the article Incredible Edibles. And now in The sorcerer's apprentices - A season in the kitchen at Ferran Adria's ElBulli.
I was thinking about how water drops evaporate and came across Leidenfrost effect . A line in that article about dipping wet hands into molten lead made me ask if this is the effect that lets some people dip into boiling vat of oil for picking out pakoras with bare hands . Sure enough
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